Does photoelectrocatalysis by TiO2 work?

BACKGROUND: This paper examines TiO₂ photoelectrocatalysis (PEC), a process that increases the efficiency of TiO₂ photocatalysis (PC) by applying a potential to separate the UV‐generated charge carriers whose recombination typically limits photonic efficiencies of conventional photocatalysis. RESULTS: Four representative photoelectrocatalytic reactions, nitrophenol oxidation, oxalate degradation, E. coli inactivation and dye decolouration were considered. For all four, a small applied potential raised the rate of pollutant removal by TiO₂ electrodes. Because the improvements were probably insufficient to make PEC technologically viable except in niche applications, rates of pollutant removal by PEC and by PC using TiO₂ particle dispersions were directly compared. PEC rates were not significantly larger than rates of PC by dispersions. CONCLUSION: Discussions of the implications of these conclusions focus on whether PEC is currently limited by reactor design (irradiation geometry, or mass transfer) or by electrode materials. It is inferred that the performance of present electrodes is not limited significantly by mass transfer constraints. Since the choice of electrode materials (sol–gel or thermal electrodes) has been shown to influence PEC efficiency, recent results on titania nanotubes (TNT) are reviewed. It is concluded that the enhancement factors—the PEC:PC ratio—of TNT electrodes are no higher than those of conventional materials. Copyright © 2011 Society of Chemical Industry     

Lipidomic analysis of fats and oils – a lot more than just omega‐3

Edible oils and fats are among the most abundant cooking ingredients in the world, and are an important part of a healthy balanced diet, especially if they are high in omega‐6 and omega‐3 polyunsaturated fatty acids. Rather than just the total fatty acid compositions, the analysis of individual lipid species within these oils and fats has become increasingly important. Within the past decade several mass spectrometric lipidomics methods have been adapted and applied to the analysis of edible oils and fats. These methodologies are vital for the analysis of a plethora of lipid species that will be important for numerous health and sustainability issues in the future.     

An integrated model of weekday stress and weekend recovery of students.

In previous research on psychological stress recovery, recovery activities and recovery experiences have been studied separately rather than jointly. The present study advances previous knowledge about stress recovery by integrating the effects of these separate recovery constructs within a single study and examining them outside the work context. We propose and test an integrated model of the stress-recovery process that includes weekday stressors and weekend recovery activity behaviors, psychological recovery experiences, and recovery outcomes. Undergraduates (n = 221) from a Midwestern university reported on Friday about stressors experienced during the week, followed by a weekend during which recovery could occur. On Monday they reported their weekend activities and their current well-being. Results suggest that participating in specific recovery activities during a weekend and accompanying specific subjective recovery experiences reduce negative psychological outcomes. Future research and practical applications of the integrated model of the recovery process are discussed. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Reducing the greenhouse gas footprint of primary metal production: Where should the focus be?

The mineral processing and metal production sector is endeavouring to identify opportunities to improve the sustainability of its operations and reduce its greenhouse gas footprint, with improved energy efficiency receiving increased attention. However, if truly sustainable outcomes are to be obtained it is essential that a life cycle approach be adopted in evaluating these opportunities. In this paper, life cycle assessment methodology is used to indicate where in the metal production life cycle this focus on energy efficiency should be and to evaluate a number of potential opportunities for reducing the greenhouse gas footprint of primary metal production.Results from life cycle assessments of the main primary metal production processes, together with current and predicted global metal production rates, ore grades and grind or liberation size, have been used in a broad analysis to indicate that endeavours to improve the energy efficiency of primary metal production should focus mainly on the metal extraction stage, particularly for steel and aluminium. Declining ore grades and more complex ore bodies anticipated in the future can be expected to significantly increase the energy required for comminution of the main metal ores and will present opportunities for improving the energy efficiency of primary metal production. However, these opportunities will still be appreciably less than potential energy efficiency improvements in the extraction stage for these metals.     

Variability reduction through optimal combination of wind/wave resources – An Irish case study

This study presents a methodology to assess the possible benefits of the combination of wind energy with the still unexploited, but quite significant in Ireland, wave energy. An analysis of the raw wind and wave resource at certain locations around the coasts of Ireland shows how they are very low correlated on the South and West Coast, where the waves are dominated by the presence of high energy swells generated by remote westerly wind systems. As a consequence, the integration of wind and waves in combined farms, at these locations, allows the achievement of a more reliable, less variable and more predictable electrical power production. The resulting benefits are particularly clear in the case of a relatively small and quite isolated electrical system such as the Irish one. Here, in fact, high levels of wind penetration strongly increase the requirement of surplus capacity and cause a much lower efficiency for conventional thermal plants.     

Improvement of fuel properties of cottonseed oil methyl esters with commercial additives

The low temperature operability and oxidative stability of cottonseed oil methyl esters (CSME) were improved with four anti‐gel additives as well as one antioxidant additive, gossypol. Low temperature operability and oxidative stability of CSME was determined by cloud point (CP), pour point (PP), cold filter plugging point (CFPP), and oxidative stability index (OSI). The most significant reductions in CP, PP, and CFPP in all cases were obtained with Technol®, with the average reduction in temperature found to be 3.9 °C. Gunk®, Heet®, and Howe's® were progressively less effective, as indicated by average reductions in temperature of 3.4, 3.0, and 2.8 °C, respectively. In all cases, the magnitude of CFPP reduction was greater than for PP and especially CP. Addition of gossypol, a polyphenolic aldehyde, resulted in linear improvement in OSI (R² = 0.9804). The OSI of CSME increased from 5.0 to 8.3 h with gossypol at a concentration of 1000 ppm.     

Chemometric profiling of pre-climacteric Sri Lankan mango fruit (Mangifera indica L.)

There is no published information on the genotypic variation of major biochemical constituents in mango fruit endemic to Sri Lanka. Accordingly, non-structural carbohydrates, non-volatile organic acids and total phenolics were determined from the peel and pulp of pre-climacteric Sri Lankan mango cultivars (viz. Willard, Karutha Colomban, Vellai Colomban, Ampalavi, and Malgova) at three different maturity stages. Principal components analysis revealed distinct clustering of samples according to their biochemical profiles of peel and pulp at three maturity stages. Sugar concentrations generally declined with maturity in both peel and pulp except for cv. Willard. Fructose was the predominant sugar in both peel (56.2–106 mg/g dry weight (DW)) and pulp (67.4–141 mg/g DW), followed by glucose and sucrose. Starch concentration increased with maturity and was higher in pulp (26.0–55.0% DW) than peel (18.2–38.9% DW) at full mature stage. Dry matter as a proportion of fresh weight (FW) increased with maturity.     

Processing and characterization of nanostructured Cu-carbon nanotube composites

Carbon nanotube (CNT) reinforced nanostructured Cu matrix composite with a grain size less than 25 nm has been successfully fabricated via a combination of ball milling and high-pressure torsion. CNTs were found to be homogeneously dispersed into the metal matrix, leading to grain refinement with a narrow grain size distribution and significant increase in hardness.     

Searching for differences in race: Is there evidence for preferential detection of other-race faces?

Previous research has suggested that like animal and social fear-relevant stimuli, other-race faces (African American) are detected preferentially in visual search. Three experiments using Chinese or Indonesian faces as other-race faces yielded the opposite pattern of results: faster detection of same-race faces among other-race faces. This apparently inconsistent pattern of results was resolved by showing that Asian and African American faces are detected preferentially in tasks that have small stimulus sets and employ fixed target searches. Asian and African American other-race faces are found slower among Caucasian face backgrounds if larger stimulus sets are used in tasks with a variable mapping of stimulus to background or target. Thus, preferential detection of other-race faces was not found under task conditions in which preferential detection of animal and social fear-relevant stimuli is evident. Although consistent with the view that same-race faces are processed in more detail than other-race faces, the current findings suggest that other-race faces do not draw attention preferentially. (PsycINFO Database Record (c) 2010 APA, all rights reserved)